How to Identify Ionic Contamination Sources in PCB Assembly

What causes PCB failure?

Whether it's a catastrophic failure or a latent field failure, nothing is more frustrating and expensive than when a circuit board stops functioning. The design was prototyped and thoroughly tested, and yet, has problems once in full production. What happened?!

I can’t speak to every potential quality control problem that can creep into a PCB assembly process, but contamination continues to be an underlying issue for many PCB reliability problems. There are essentially two broad categories of PCB contamination, ionic and nonionic, but we will concentrate largely on the ionic contamination sources.

What is Ionic Contamination of a PCB?

Ionic contaminants are remains of flux that are left behind during the assembly process. Ionic compounds are held together by electrostatic forces and the compound itself has a zero net charge. These are composed of positively charged cations and negatively charged anions.  A simple example is table salt (sodium chloride), composed of a single positive sodium cation which lacks one electron, and a negatively charged chloride anion (Cl), which has an extra electron. 

When populating the board with components, the components themselves also can carry various ionic/conductive contaminants to your assembly including cutting oils/fluids, biocides, and corrosion preventatives. Be aware of common nonionic materials that can also affect the assembly steps – process oils, mold releases, etc. can be detrimental down the line.

Sources can originate at any point in the assembly process, so let’s start at the beginning. You’ve just received a new lot of bare boards which you will populate with the necessary components for your product.

Common Ionic Contaminants from the Bare Board Fabrication

  • Common moisture can be trapped almost anywhere in the “layering” process. This is conducive for dissociating other ionic materials which lays the foundation for conductive mishaps (dendritic growth, ECM, etc).  It is common practice to “bake” the boards to remove extraneous moisture.

Corrosion from PCB fabrication contamination 
Corrosion from PCB fabrication contamination - courtesy of Foresite, Inc


  • Etching chemicals – these are highly conductive and can be corrosive as well. They must be chemically neutralized and removed/rinsed and are well-known as sources for current leakage.

Heavy no-clean flux residue with visible copper corrosion on pcb
Heavy no-clean flux residue with visible copper corrosion - courtesy of Foresite, Inc.

Everyone is familiar with flux residues. Fluxes, whether in liquid, cored wire, or compounded as a paste, can leave residues that can cause serious reliability defects if not removed. Common conductive flux residues from the soldering process can include various unreacted activators, binders, rheology components, and saponifiers. Among these are numerous iterations of acids (abietic, adipic, succinic among others), highly basic ingredients (amino compounds), and even constituents found in “soaps” such as phosphate and sulfate ions. All of these must be cleaned from the substrate, whether by strict solvent cleaning such as vapor degreasing or by aqueous chemistries in the common batch or inline cleaners seen on the manufacturing floor.

  • Inter-layer residues – can be spread during the drilling and via plating processes.

Dendritic grown between solder pads, caused by ionic contamination on printed circuit board
Dendritic grown between solder pads, caused by ionic contamination - courtesy of Foresite, Inc.

In addition to these widely seen residues, residues from the cleaning process chemistry itself must also be removed.  This is noticed more in the aqueous cleaning systems.  Many use saponifiers to neutralize and emulsify the flux residues and make them easier to rinse/remove from the substrate.  These components themselves are highly ionic and can also enhance the dendrite and/or ECM mechanism if not removed.  In addition, corrosion preventatives and surfactants are commonly employed in these products.  This is not a bad thing in itself, but care must be taken to ensure they are removed along with the soils during the cleaning process.

Perform Ionic Contamination Testing to Find Contamination 

Poor quality control from PCB fabrication, to the soldering and component population, to the final cleaning stages, are all potential sources of contamination. Many of these can be found by ionic contamination testing and analysis such as ROSE testing, ion extraction, and chromatography, as well during initial high humidity validation testing at the beginning of the project. 

Strict quality control and standard operating procedures during the PCB assembly and the stages of assembly manufacturing and validation testing can go a long way in preventing a reliability nightmare. Just think – simple mishandling of a part by an operator not using gloves can transfer salts and oils from skin to the substrate that could potentially be catastrophic for your item!

Techspray offers a full line of flux removers that are highly effective at removing ionic contamination before they can cause board failures. Techspray G3 Flux Remover is a powerful, nonflammable solvent that effortlessly blasts away residues.

PWR-4 Flux Remover is designed to replace toxic solvents like n-propyl bromide (nPB), that are commonly used in vapor degreasers and ultrasonic equipment.

Eco-dFluxer SMT300 water-based flux remover is designed to clean electronic circuit boards, even with sensitive metals, in a batch or inline cleaning system.

For more information, contact Techspray at +31 88 1307 400 or send us a message here.

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